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Microscopic Reversibility

2 Equilibrium Constant: Mathemati

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3. Equilibrium Constant Magnitude

7. Manipulating K Expressions

1 pts 2req

1 pts 2req

O

4. Exploring Equilibrium: Nitrogen 1 pts req

5 Writing Equilibrium Expressions

6. Writing Equilibrium Expressions. 1 pts reg

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Due Jun 22 at 11:55 PM

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8. Calculate K for Rearranged Equ 1 pts req

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9 Writing Equilibrium Expressions 1 pts req

Dinitrogen tetraoxide is a colorless gas at room temperature. It can dissociate into nitrogen dioxide, which is a reddish brown gas.

N₂O4(9) 2 NO₂(g)

Three experiments were run starting with different initial amounts of N₂O(g) (N₂O4lo in the table). The systems were allowed to reach

equilibrium and the concentrations for each gas were measured (in units of moles/Liter).

Review Topics

References]

Use the References to access important values if needed for this question.

For each of the boxes below, calculate the ratios indicated by the column heading. This will show the mathematical relationship that exists.

between the concentrations of NO and N₂O4 at equilibrium.

Be sure to round to the correct number of significant figures.

Exp [N₂04]0 [NO₂] [N₂O4] [NO₂] / [N₂O4] 2 [NO,] / [N₂O₁] [NO₂]2/[N₂O4]

1

2.85 2.1

2

2.56 1.7

2.24 1.3.

3

3.5

3.0

2.4

Based on your calculations, indicate whether each statement is True (T) or False (F):

1. Each experiment started with a different initial concentration of N₂O4

2. The ratio ([NO₂1/[N₂O4]) is equal to a constant value.

3. The ratio (2 [NO₂]/[N₂O4]) is equal to a constant value.

4. The ratio ([NO₂)/(N₂Oa]) is equal to a constant value.

5. Each experiment reached a different set of equilibrium concentrations.

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