Inorganic Chemistry Homework Help

3 - Names of Molecular Compounds(5pts)Complete the table with the name for the compounds. (18pts)Complete the molecular compound structure table and upload an image of the completed table here.

Which of the following correctly places the ligands in their order in the spectrochemical series? Da.F-< Cl-<H2O<NH3 b.CI-< Br-< NH3 < H2O OCI-< Br-<NH3 < H2O Od. Br-<I-< phen<H20 De.1-< Cl¯<H20< en

Which of the following Newman projections represents the least stable (highest energy)conformer of 1,2-dibromoethane? Select one: a. A is the least stable conformer b. B is the least stable conformer c. C is the least stable conformer d. D is the least stable conformer e. E is the least stable conformer

Which of the options listed below is the correct IUPAC name for the following molecule. Select one: a. 6-ethyl-4-methylhept-2-ene b. The correct IUPAC name is not listed. c. 6-ethyl-4-methylhept-2-yne d. 2-ethyl-4-methylhept-5-yne e. 4,6-dimethyloct-2-yne f. 3,5-dimethyloct-6-yne

A characteristic of all ligands is that they are: O anions electron pair accceptors O Lewis acids neutral molecules Lewis bases

Which of the following ligands is not a chelating agent? oxalato O protoporphyrin(IX) trimethylphosphine O bipyridine ethylenediamine

Consider the diagram shown below for a dimetallic complex. Which of the following statements is not true regarding this structure? Contains two bridging ligands. Contains ligands derived from cyclopentadienyl. Contains ligands derived from the phosphine molecule. The complex is a derivative of ferrocene. O Contains ligands in an eclipsed conformation.

Which metal complex ion is expected to be subject to a Jahn-Teller distortion? \text { a. }\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+} \text { b. }\left[\mathrm{Cr}(\mathrm{en})_{3}\right]^{3+} \text { C. }\left[\operatorname{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+} \text { d. }\left[\mathrm{Cr}(\mathrm{CN})_{6}\right]^{3-} \text { e. }\left[\mathrm{Cr}(\mathrm{bpy})_{3}\right]^{3+}

What is the best name for the coordination compound with formula Na2[PdCl6]? O disodium hexachloropalladium(IV) sodium hexachloropalladate(IV) disodium palladium(IV) hexachloride sodium hexachloropalladium(IV) disodium hexachloropalladate(IV)

What are the bond order(s) for nitrate functioning as a counterion? 1.33 only Both 1 and 2 Both 1.5 and 2 O 1.5 only Both 1 and 1.5

Zn2+complexes are atypical of d-block complexes in general. Which answer below is correct and supports this statement? Zn-T complexesare always octahedral. D. Zn-+ complexes are always tetrahedral. Zn2+ complexes are paramagnetic. d. Zn2+complexes tend to be colourless. e. Z is one of several oxidation states of Zn.2+

Which of the following observations for the complex ion [Cr(CN)6] is the most likely to represent the observed magnetic moment of the complex. [Cr(CN)6] is diamagnetic. -[Cr(CN)6]3is paramagnetic with Hobs 2.82 HB [C{CN)6]3-is paramagnetic with Hobs = 4.90 HB d. [Cr(CN)6] is paramagnetic with Hobs = 1.73 HB =- [Cr(CN)6]is paramagnetic with Hobs 3.87 HB

5. In the octahedral d complex, VCI3, the two lowest energy transitions occur at 6600 and13300 cm1. Use a Tanabe-Sugano diagram to calculate the values of the crystal field splitting and Racah parameters and work out the frequency of the higher energy transition.

10. considering the nephelauxetic effect and using the Jørgensen approximation for B,3+Which of the complexes [Rh(en)3]* and [Rh(H2O)6]3+ is more covalent and has more electronic cloud expansion (B) if you know that the value of K for Rh(III) is 0.30, while the value of h for (en) = 1.29 and for H2O = 1.0( where (1-B)=h.K))

1. There are three transitions in the UV-visible spectrum of [Co(NH3)61< at 10700, 17500 and28200 cm. Assign electronic transitions to the three absorptions and calculate values forA, x and B'.The value of B for the free Coʻ2+ion is 1040 cm-1Why is this different from B'?

The maximum number of electrons that can be accommodated in sp3 d4 hybridised set of orbitals is: 8 O 16 32 10

Consider the complex ion comprising Co() as the metal centre coordinated to two ethylene diamine fig ands and one oxalato ligand. The donor set of this complex would be:50to this answer.NON O N50 O N204 O N6O N202 O N402

What type of cisplatin-DNA interaction is the most commonly occurring? O interstrand crosslinking between oneguanine and one adenine nuclebase O 1,3-intrastrand crosslinking between one guanine and one adenine nucleobase interstrand crosslinking between two guanine nuclebases 1,2-intrastrand crosslinking between adjacent guanine nucleobases O 1,2-intrastrand crosslinking between adjacent guanine and adenine nucleobases