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Q2.

Assess if ammonium chloride NH4Cl (s) can be spontaneously transformed into ammonia and HCl gas at 25°C, using values below.

Sº (JK ¹mol-¹)

94.6

192.5

186.9

I.

II.

Substance

NH₂Cl (s)

NH,(E)

HCI (g)

AH (kJ/mol)

-314.4

-46.1

-92.3

Calculate respectively the entropy and enthalpy change of the process.

Calculate Gibbs free energy change at the particular T and check if it indicates spontaneity

Fig: 1