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Recently Asked Physical Chemistry Questions
Expert help when you need it- Q1:8 calculate the ionization energy of the li 2 ion 9 show that the wavefunctions 100 and 200 for the hydroge 10 calculateSee Answer
- Q2:8 calculate the ionization energy of the li 2 ion 9 show that the wavefunctions 100 and 200 for the hydrogen atom areSee Answer
- Q3:6.1 The problem has the potentials vs SCE whil pourbaix diagram has potential vs SHE, so you to convert via table 3.2.See Answer
- Q4:Problems 1. The following electrode potentials were observed after a 1-year immersion period in natural seawater of pH 8.0 [20]:See Answer
- Q5:5. In the interpretation of Pourbaix diagrams, corrosion is considered to occur when the concentration of dissolved metal ions attains a minimum concentration of 1.0 x 10-6 M. Suppose that a 0.50-cm² sample of aluminum immersed in 1.0 L of an aqueous solution corrodes at a constant current density of 100 μA/cm². How long will it take to produce a concentration of 1.0 x 10-6 MAI³+?See Answer
- Q6: Problem 3Two chemicals, A and B when mixed produced an almost perfect ideal solution. The vapour pressures of A and B were 25.4 kPa and 96.1 kPa respectively at 298 K. (b) Indicate on your phase diagram the compositions (xA, YA, ZA) of the piston at the given pressure. What is the total number of moles of A and the total number of moles of B in the piston? What is the number of moles of gas and number of moles of liguid in the piston? What is the number of moles of gaseous chemical A and liquid chemical A in the piston? What is the number of moles of gaseous chemical B and liquid chemical B in the piston? What is the approximate volume (in liters) of the piston? (hint: ignore the volume of the liquid). (a) Draw a pressure composition phase diagram for 298 K (full marks if drawn correctly in Excel). A solution containing a total of 20 mmol = na + n(b)was prepared in a piston with the composition of Z(A) = 0.6481. The total pressure on the piston was adjusted to 40.66 kPa.See Answer
- Q7: which element has the largest bond atomic radius? A. Tungsten, W B Osmium C Rhenium D Tantalum E hafnium HF The coordination sphere of complex consists of A. coordination of steric numbers B. ligands C.metal ion only D. the cental metal ion the ligands bonded to it 5.primary and secondary valenciesSee Answer
- Q8: which of the following displays geometrical isomerism ) square-plunar ERH (U)a clz square planar [P+ Len)272 Octunedral. Octahedral rWINHa)CI]2tSee Answer
- Q9: B.NumePOllowing metals 1, Ch torinepen ta aqua ehh liro Ch ruminiun nchiorpenta a qu a Ch rumi um (Ll!) 1on Chlonde 3. Penta aq -vh ch lor1) ch lurideSee Answer
- Q10: Problem A: Below is shown a plot of the natural logarithm of the diffusion coefficient versus reciprocal of the absolute temperature, for the diffusion of iron in chromium. Determine values for the activation energy(in J/mol) and pre exponential (in m?/s). See Answer
- Q11: Need Overall cell reaction for sodium sulfate electrolysis. Anode and cathode are given. Here are the half reactions for anode and cathode: \text { Anode: } \operatorname{Cu}(\mathrm{s}) \longrightarrow \mathrm{Cu} \wedge 2+(\mathrm{aq})+2^{\wedge} \mathrm{e}-\text { and cathode: } 2 \mathrm{H} 2 \mathrm{O}(1)+2 \mathrm{e}^{\wedge} \rightarrow \mathrm{H} 2(\mathrm{~g})-2 \mathrm{OH}-(\mathrm{aq})See Answer
- Q12: Use the periodic table to answer the following questions. (Round atomic masses to the nearest tenth unit.) \text { a. What is the molar mass of } \mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{2} \text { ? (. } 5 \text { point) } \text { d. What is the molarity of } 48.6 \mathrm{~g} \text { of magnesium ( } \mathrm{Mg} \text { ) ions in } 2 \mathrm{~L} \mathrm{H}_{2} \mathrm{O} \text { ? (.5 point) } \text { What is the number of molecules of } 140 \mathrm{~g} \text { of } \mathrm{CO} \text { ? } What is the number of moles of 27.6 g of lithium (See Answer
- Q13: a. What is the difference between the empirical formula and the molecular formula? (.5point) b. How does one determine the molecular formula from the empirical formula? (.5 point)See Answer
- Q14: a. How is the percent composition by mass determined? (.5 point) b. Determine the percent composition of each element in MgCl,. (1 point) i. Magnesium (Mg): (.5 point) ii. Chlorine (CI): (.5 point) c. Calculate the empirical formula from the given percent compositions. 82% nitrogen (N), 18% hydrogen (H) (2 points)See Answer
- Q15: a. How can one tell if a chemical reaction is balanced? (.5 point) b. What information does a complete ionic equation give that the balanced equation doesn't show? (.5 point) c. What information does a net ionic equation give that the complete ionic equation does not show? (.5 point)See Answer
- Q16: Problem 5.19: Using the data in Table 5.2, compute the value of D for the diffusion of zinc in copper a t650°C. Show your work as you would on an exam: equations in symbols, values of the parameters with units, any unit conversions, final answer with units.See Answer
- Q17: We have spent some time discussing reactions that occur in aqueous media and devoted some attention to the properties of water that make it unique. Now consider the power required to drive the hydrologic cycle, assuming that annual global rainfall averages 1 m across the approximately 5.1 × 1014 m² of earth's surface. What is the energy required to drive the hydrologic cycle? How does this compare with incoming solar radiation and world energy consumption? Consider the following data: Latent heat of vaporization = 2465 kJ/kg for water at 15°C.In 1987 world energy consumption was estimated at 3.3 x 107 kJ Incoming sunlight absorbed at 168 W/m? at earth's surfaceSee Answer
- Q18: 1. Which test tube (1 or 2) initially had the most solid precipitate? Why was there moreppt. in this test tube? (Hint: Which solution initially contains more free floating \left.\mathrm{C}_{2} \mathrm{O}_{4}{ }^{2-} \text { ions? } \ldots . \mathrm{K}_{2} \mathrm{C}_{2} \mathrm{O}_{4} \mathrm{Or} \mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4} ?\right) Test tube 2 had the more solid precipitate because the dissociation of K2C2O4 is more feasible than H2C2O4 Thus in case of potassium oxalate there are more oxalate ions present than that of oxalic acid . Hence by addition of CaCl2 test tube2 would produce more precipitate.See Answer
- Q19:4) Calculate the mass of oxygen produced from 12.3 g of nitric oxide.See Answer
- Q20: Problem 1. Uranium has two main isotopes, 235 U and 238U. Fill in the blank cells of the following table. The value-sin the white cells can be obtained with the help of a little online searching. The value in the yellow cell should be calculated, and you need to show the calculation. Nothing needs to be done with the gray cells. 235U is the-isotope needed to make a uranium fission atomic bomb. See Answer
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