# chemical thermodynamics homework help

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• Q1: Fluid force on vertical plate: Determine the total force on the vertical plate that holds backwater (forces on plate are in equilibrium, and the plate is stationary) stored in a large rectangular tank at a depth from 0 to 20 meters, as indicated in the Figure 1 below. Consider the plate is held in place by pins at the A and B positions. The width of the plate (distance into the page) is 50 meters. Provide the answer in metric units (Newtons). See Answer
• Q2: . A tank is filled with 100.0L of water which contains a solute A. The initial concentration of A in the tank is 10 g/L. Pure water flows into the tank at a rate of 2 L/sec. The solution flowing out has the same flow rate. We can assume that the concentration is dilute enough that the concentration of species A does not impact the volume of the solution so the volume in the tank will remain constant. (a) Derive an expression for concentration of A as a function of time. (b) How long will it take to reduce the concentration in the tank my 90% ? (c) How long will it take to reduce the concentration in the tank by 99%?See Answer
• Q3: 4. Evaluation of tank wall thickness: Your boss tells you that the company has an unused 2.2 m3carbon steel tank (4 meters long) that he wants you to evaluate as to whether it is suitable foruse as a pressurized stirred tank reactor. He says the carbon steel walls of the tank have a thickness of 6 mm, and you are able to find that the tensile strength (ơtens) O of carbon steel is 260MPa. If your boss says you need to have a 2X safety factor in this pressure calculation, then what is the maximum working pressure that you calculate that this tank can be subjected to without any risk of rupture? Give your answer for the working pressure in psig. You will first need to calculate the tank diameter from the information given in the problem.See Answer
• Q4: As you already know, the units of -r, are always in terms of concentration per unit a me (mol/m/s), and the units for k will vary with the order of the reaction. So, a) write the power law for a 0th, 1st, 2nd, and 3rd overall reaction order and b) the units for k for each order (A products)See Answer
• Q5:4.11 Steam enters a one-inlet, two-exit control volume at location (1) at 360°C, 100 bar, with a mass flow rate of 2 kg/s. The inlet pipe is round with a diameter of 5.2 cm. Fifteen percent of the flow leaves through location (2) and the remainder leaves at (3). For steady-state operation, determine the inlet velocity, in m/s, and the mass flow rate at each exit, in kg/s.See Answer

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