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Recently Asked Applied Chemistry Questions

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Q1:SCH4U Assignment 8 Name: Lab Activity: Identification of Crystalline Solids Scenario: You are a chemist working in a laboratory where unknown samples are given to you to test and identify. Your first assignment is to identify five unknown samples and state their respective type of crystalline solid. The experimental results are for you to examine and make your final conclusions. Samples: Sample 1 Sample 2 Sample 3 Sample 4 Part A- Chemical Analyses In addition to the visual observations you can make from the photos of the samples, the following results are from analyses of the samples: Sample 1: Odour- Odourless Solubility in water- soluble Solubility in hexane- insoluble Electrical conductivity of solid- no conduction Electrical conductivity in molten state- conducts Sample 2: Odour- Odourless Solubility in water- insoluble Solubility in hexane- insoluble Electrical conductivity of solid- conducts electricity Electrical conductivity in molten state- conducts Sample 3: Odour- Odourless Solubility in water- insoluble Solubility in hexane- insoluble Electrical conductivity of solid- no conduction Electrical conductivity in molten state- melting point is too high. No results. Sample 4: Odour- sharp aromatic odour Solubility in water- insoluble Solubility in hexane- soluble Electrical conductivity of solid- no conduction Electrical conductivity in molten state- no conduction Questions 1. Give two qualitative observations for each sample upon closer examination of the respective photos. 2. Sample Four was the only sample that contained an odour. What does this suggest about the ease with which the particles can leave the solid with respect to the strength of the intermolecular forces of attraction between the particles? 3. Which sample has mobile electrons for which to conduct electricity? 4. Sample Four was the only one that was soluble in a nonpolar solvent. What does this suggest about the polarity of the molecule in Sample Four? 5. Sample One was soluble in water and in its molten state conducted electricity, but in its solid state it did not conduct electricity. Electrons only flow in solids to produce current electricity. What types of particles does the experimental evidence point to the makeup of this sample? 6. What evidence is there to support the formation of ionic or molecular liquids of nonpolar crystals? 7. What could you deduce about the strength of the forces of attraction between the particles, in Sample 3, compared to the other samples? 8. Give 3 more physical tests to help you in your analysis of these samples and their subsequent identification. Conclusion Identify each sample as a metallic crystal, ionic crystal, covalent network solid crystal or a molecular crystal. Part B- Chemical Reactions Match each sample to each of the following descriptions of chemical reactions. Sample (i) High pressures and temperatures on organic material over a long period of time. Sample (ii) Reaction between an alkali metal and a halogen. Sample (iii) Synthesis of an organic compound. Sample (iv) Oxidation of sample eliminates the lustrous quality. SCH4U Assignment 7 Name: Hand draw the Lewis structure and VSEPR diagram for the following molecules. Show bond polarity and state the geometric shape and molecular polarity. The first one is done for you. Lewis Structure VSEPR Diagram Shape & Molecular Polarity 1) NH3 5- : ï N H 8 + - Trigonal pyramidal - Polar 2) BeCl2 3) ClO3 -1 4) BrCl3 5) ClO2 -1 H + N H 6) KrCl2 Lewis Structure VSEPR Diagram Shape & Molecular Polarity 7) KrBr4 8) PCl5 9) XeSBr4 10) SF6 SCH4U Assignment 6 Name; Draw the Lewis Structures for each of the following molecules. Be sure to show single/double/triple bonds using proper dashes and also include lone pairs of elections where necessary. H2S SO3 CH2Br2 HCN NH4+1 PO4-3 NO3-1 CO3-2 PBr3 NO2-1 N2 BF3 * SCH4U Assignment 5 Name: 1. Draw the energy-level diagrams for the following: a) Br b) Zn+2 c) Kr 2. Write the electron configuration for the following: a) Ag+1 b) Sr c) V+5 3. Write the shorthand electron configuration for the following: a) Po+2 b) Ni c) Pt+2 Organic Reactions Name: Complete the following reactions using structural formulas, state the type of reaction, and write the name of the compound under each organic molecule: 1. Type: CH3-CH2-CH3 + 12 UV Light 2. Type: OH O = - heat CH3-CH2-CH2 + CH3-CH2-CH-C-OH > H2SO4 CH3 3. Type: CH3 1 CH2=CH-CH2-CH3 1 + HF > CH3 4. Type: 0 = H2SO4 CH3-N-C-CH2-CH3 + H2O 1 I CH3CH-CH3 5. Type: F - CH2-CH2-CH3 + LiOH 6. Type: OH 1 CH3-CH-CH-CH3 - + (0) > CH2-CH3 7. Type: OH 1 H2SO4 CH2-CH2-CH2-CH-CI - CH3 8. Type: CH2-CH3 CH3-CH-CH2-CH=CH2 - H2SO4 + H2O 9. Type: 0 heat CH3-CH-C-CH3 - CH2-F + H2 > pressure 10. Type: CH3 - CH=C-CH2-CH-CH-CH3 - 0 + 2 Br2 > SCH4U Name: Alcohols, Ethers, Aldehydes, Ketones, Carboxylic Acids, Esters, Amines, Amides Part A: Draw the structure for the following organic molecules: [16] 1) 2-chloro-2-iodo-3-ethylhexanoic acid 2) N-ethyl-N-methylpentamide 3) 2-ethylbutylbenzoate 4) dipropyl ether 5) 3-isoproply-4-fluorocyclohexanone 6) 2,2-dibromo-4-phenylpentanal 7) 2-isobutyl-1,5-octanediol 8) N,N-difluoro-2-iodobutan-2-amine Part B: Write the proper name for the following organic molecules: [16] 1. 2. 0 Br Be CH -C- CH3 1 CH3 4. CH3-CH2-CH2-CH2-O-CH3 3. OH CI CH3 1 1 CH-CH-CH-CH3 1 OH OH 0 11 CH-O- CH2-CH-CH3 6. CH3 5. CH3 1 CH3 Br-CH-CH2-C- CH-CH CH3F 0 1 1 11 7. 0 11 HN-C-CH2-CH2-CH3 1 CH2 1 CH3- CH-CH3 8. F CH- CH2-CH-CH3 I -N 1 1 0 5 0 11 CH3-CH-CH-CH-CH2-C-OH CH3- CH-CH3 Hydrocarbon Nomenclature Name: Give the structure for each of the following organic compounds: 1. butane 6. 3,3-dimethyl-1-butene 2. 3-ethyl-2-methyloctane 7. 3,3,4-trimethyl-1-pentene 3. 4-isopropylnonane 8. 3-bromo-1-pentyne 4. 2-iodo-2,4,4-trimethylpentane 9. isopropylbenzene 5. 1,2-dibromocyclohexane 10. 2-phenyloctane Give the IUPAC name for each of the following structures: 1. H3C CH3 CH3 CH3 2. H3C CH3 CH3 CH3 F 3. CH3 4. H2C CH3 Br CH3 H H 6. H3C H3C CH3 7. CH3 8. HC CH3 Br 10. 5. CI H3C CH3 9. H3C BrSee Answer
Q2:/n Laboratory Worksheet 2.2 The 'iodine clock' reaction International Foundation Year Science, Engineering and Computing Pathway Tutor: Dr Kartheek Sooda The Iodine Clock lab will be held in the Leslie Silver building Remember to bring your lab books with you. Before the lab, you need to read the relevant parts of your textbook: Chapter 22 pp. 324 - 340 Also, answer the following pre-lab questions: 1. What is the role of H2O2 in the reaction? 2. Write down the steps for deducing Order of Reaction from raw data (with known initial concentrations). 3. Construct a table to enable you to record the reaction time for each reaction mixture (1-7) The Partial Report should be submitted via Turnitin This submission needs to include: Introduction ○ Cover page ○ O Results (graphs can be produced using Excel, or inserted as photographs) Introduction The equation for the reaction being studied is as follows: H2O2(aq) + 2H(aq) + 21¯(aq) → 2H2O(l) + I2(aq) The aim of this practical is to determine the order of reaction with respect to the concentrations of: • hydrogen peroxide • H+ ions • iodide ions. The reaction takes place in a solution of sodium thiosulfate and starch. As soon as the iodine is produced it reacts with thiosulfate ions to produce iodide ions: 2S2O3²¯(aq) + I2(aq) → S406²˜¯(aq) + 2Ã¯(aq) This means that the starch solution cannot react with the iodine and does not turn blue-black. However, when all the sodium thiosulfate solution has reacted, the iodine formed reacts immediately with the starch and the solution turns blue-black. Therefore, the rate of reaction is inversely proportional to the time taken for the blue-black colour to disappear (i.e. rate time The reaction is started by the addition of the required amount of potassium iodide solution each time, followed by rapid mixing. Safety Wear eye protection at all times. Sulfuric acid is an irritant. Apparatus (per group) 25.0 cm³ of 0.1 mol dm³ potassium iodide solution • 25.0 cm³ of 0.5 mol dm³ sulfuric acid • 25.0 cm³ of 0.1 mol dm³ hydrogen peroxide solution • 10 cm³ of 0.01 mol dm³ sodium thiosulfate solution • 10 cm³ of 0.2% starch solution • • 10 cm³ measuring cylinders or burettes containing the above solutions seven test tubes • stopwatch • distilled water • eye protection Procedure 1 The reaction mixtures are given in Table 1 below. Construct a results table for recording the time taken for each reaction mixture. Test Volume/cm³ tube KI H2SO4 H2O2 Na2S2O3 Starch Distilled Total solution water 1 3.0 3.0 3.0 1.0 1.0 4.0 15.0 2 2.0 3.0 3.0 1.0 1.0 5.0 15.0 3 1.0 3.0 3.0 1.0 1.0 6.0 15.0 4 3.0 2.0 3.0 1.0 1.0 5.0 15.0 5 3.0 1.0 3.0 1.0 1.0 6.0 15.0 6 3.0 3.0 2.0 1.0 1.0 5.0 15.0 7 3.0 3.0 1.0 1.0 1.0 6.0 15.0 Table 2 Reaction mixtures. 2 Make up the reaction mixtures as shown in the appropriate table above, but without the potassium iodide and the sulfuric acid (IRRITANT). Use a separate Comboplate well or labelled test tube for each mixture. 3 Add the potassium iodide and acid, as shown in the table, to the first mixture. Start the stopwatch. 4 When the blue-black colour appears, stop the watch and record the time. 5 Carry out the other six experiments and measure the time taken for each reaction. 1 6 Calculate the value of for each reaction mixture. time Questions 1 1 Why do we calculate the value of for each reaction? time 2 Why is water added to the reaction mixture? 3 State which experiments are used to determine each of the following: 4 a the effect of [I] on the rate of reaction b the effect of [H*] on the rate of reaction с the effect of [H2O2] on the rate of reaction. Determine the order of reaction with respect to the concentration of each of the three reagents. Explain your answer. 5 Write the rate expression for the reaction. 6 a Write an equation for the rate-determining step. b Why is this different from the stoichiometric equation?/nCalibri Regular (Be B àÅ× | • A× | Ev providing a quantitative basis for kinetic analysis: A FI > ITT Test Volume (cm3) tube Time (s) 1/time (S-1) H202 Na2S2O3 Starch Distilled Total Solution Water =2 1 3 1 1 4 15 15 0.066667 33332 3456 1 1 5 15 22 0.045455 1 1 6 15 27 0.037037 1 1 5 15 39 0.025641 1 1 6 15 52 0.019231 1 1 5 15 60 0.016667 7 1 9 115 59 0.016949See Answer
Q3:21. For this question you will be writing a properly formatted lab report with headings for two sections. Your task is to create an observation table based on the experiment and complete the calculations. [7 marks]/nThe Mole Lab Experiment Purpose: The purpose of this lab is to determine the number of moles of two different samples. Materials: • mass balance • 100 mL beakers • plastic spoons • sample 1: salt (NaCl) • sample 2: sugar (C12H22O11) Procedure: 1. Place an empty 100 mL Beaker on a balance and record the mass in grams. 2. Place sample 1 into the beaker and place it on the balance and record the mass in grams. 3. Place another empty 100 mL beaker on a mass and record the mass in grams. 4. Place sample 2 into the beaker and place it on the balance and record the mass in grams. Experiment: Sample 1 An empty beaker on a balance measuring 98.3 grams and a beaker containing salt on a balance measuring 104.5 grams. Sample 2 An empty beaker on a balance measuring 97.5 grams and a beaker containing sugar on a balance measuring 102.1 grams. Observations Create your own observations table with the following headings: • mass of empty beaker • mass of sample + beaker • mass of sample • molar mass of sample (Note: include units where applicable.) Calculations Find the moles of each sample. Solve the problem using the GRASS (GRASP) methodSee Answer
Q4:19. Scientists found that an 800.00 mg tablet of acetylsalicylic acid (C9H8O4) contains 200.00 mg of carbon and 25.2 mg of hydrogen. The remaining mass is oxygen. Determine the percent composition of acetylsalicylic acid. [3 marks]See Answer
Q5:18. Scientists at a company called ENERGYUP created an energy drink that contains 40.0 mg of caffeine ( C8H10N4O2). Calculate the amount of moles of caffeine in the energy drink. Show your full solution. [3 marks]See Answer
Q6:17. Calculate the number of moles for the following questions. Pay attention to significant figures. Show your work. [6 marks] a. 2.70 × 10³ g of water (H₂O) b. 1035 g of lead (Pb)See Answer
Q7:15. The following observations were made during a chemical reaction involving three unknown metals. Analyze the table to help you answer the questions that follow. [5 marks] Reaction Metals Reaction with hydrochloric acid with water Unknown A Unknown B Unknown C No reaction No reaction The reaction occurred immediately within 1 minute. A large amount of gas was produced and released. Some bubbles were observed on the surface of the metal after 2 minutes. Reaction with vinegar Immediate production of bubbles on the surface of the metal No reaction There was an immediate, rapid production of Small bubbles formed on No reaction bubbles on the surface of the metal. The entire piece the surface of the meta of metal had reacted within 5 minutes. a. List the metals in order from most reactive to least reactive. b. Write a short statement justifying the order of your list. c. If all of the metals were located in the same period on the periodic table but in different groups, which would have the highest group number? Explain your answer with a short statement related to periodic trends.See Answer
Q8:7. What effect does temperature have on states of matter. Use your knowledge of particle theory to describe how to move between the states of matter and the effect of forces on the particles. You may choose to draw a diagram to explain your thinking. [3 marks]See Answer
Q9:6. Draw a Lewis structure for each of the following compounds. Make sure your diagram clearly distinguishes the type of bonding. Label your structure as "ionic" or "covalent." If it is covalent, identify the single, double, and triple bonds, if present. [12 marks] (Note: both ionic and covalent types have been included.) a. CF4/nb. N₂H2 c. NI3 d. CaCl2See Answer
Q10:1. Atoms, ions, and molecules are the three types of particles that make up matter. How are they similar? How are they different? Share at least 3 similarities and/or differences in your response. Point form is acceptable. [3 marks]See Answer
Q11:10:01: X ||| O b 0 c. O d. H H но- H HO H HO HO H HO Via Web Browser Н Jump to... Previous page H CH₂OH -Н -OH -Н -ОН CH₂OH | Lab Quiz #4 COOH -Н OH H -OH CH OH CH₂OH -Н -OH -Н -OH CH₂OH ..1 56: E8 32 в о Next pageSee Answer
Q12:Question 5 Not yet answered Points out of 1 Flag question The molecule below is D-o-CH Select one: O a. butyl methyl ether O b. butyl ether c. cyclopropyl methyl ether d. a hemiacetal O d.See Answer
Q13:Question 38 Not yet answered Points out of 1 P Flag question What is the relationship of these compounds to each other? I. H- COOH HO- CH₂ COOH HOM -он -OH CH₂ Select one: II. HO- HO COOH CH₂ III. a. Compounds II and III are enantiomers; compound I is not related to II and III. O b. Compounds I and II are enantiomers; III is a diastereomer of I and II. c. Compounds I and II are enantiomers; compound III is not related to I and II. Od. These three compounds are not relate other, they only look similar.See Answer
Q14:Question 30 Not yet answered Points out of 1 P Flag question Shown below is a cyclic form of D-glucose. This structure is classified as CH₂OH H HO H ОН H 0 Previous page H OH H OH Select one: O a. a-D-glucopyranose b. b-D-glucofuranose O c. a-D-galactopyranose O d. b - L-glucopyranose a jeSee Answer
Q15:Question 19 Not yet answered Points out of 1 P Flag question What is the major organic product of the following reaction? || CH₂CH₂C-H + H₂ Select one: a. CH₂CH=CH₂ O b. CH₂CH₂CH₂OH OC. CH3CH, CH3 d. CH3CH₂COOH Previous page I Lab Quiz #4 Jump to... Pr Next pageSee Answer
Q16:Points out of 1 P Flag question Which of these compounds is a properly named 2° alcohol? Select one: a. 1,3-Propandiol O b. 2-Methyl-3-methyl-3-pentanol O c. 1-Propanol H H- H HH H H H m- -C- O d. 3-Hexanol m H B -- 8 -C- 8 D H -O HH -- Q сSee Answer
Q17:Question 9 Not yet answered Points out of 1 P Flag question The product of the nucleophilic substitution reaction below is *SCH₂CH₂ Select one: O a. O b. O C. CH₂CH₂CH₂SCH₂CH₂ S-CH₂-CH; CH₂-CH-CH₂ Br ! CH₂CCH, S-CH₂-CH; O d. CH₂-CH₂-CH₂-CH₂-SH Br CH;CHCH; Previous page ob Quix #4 Next pageSee Answer
Q18:4. Given the following experimental observations (errors determined as standard deviations): h₁ = 15 + 1mm (manometer reading) h₂ = 9±1mm (manometer reading) P₁ = 18.6 ± 0.1 psia Q=0.308 ± 0.06 ft³. (min)-¹ V = 1 + 0.05 gal m = 8.2 ± 0.05 lbm Calculate the following derived variables and their best-estimate uncertainties. Present the results in the form of x = x, ± 8x. a. Pressure drop reading from the manometer. AP(mmHg) = h₁ - h₂ [6±1.4mmHg] b. Pressure drop conversion from mmHg to psia. [0.12±0.027psi] c. Pressure ratio: [1.006±0.008794] d. Specific Gravity: SG = Psample Pwater (for liquids) [0.98+0.05] e. Valve sizing coefficient: C₂ = Q * SG So for Qin ΔΡ gal minute and AP in psi [6.7+1.5]See Answer
Q19:3. Consider a hot automotive engine, which can be approximated as a 0.6 m high, 0.3 m wide, and 0.9 m long rectangular block. The bottom surface of the block is at a temperature of 90°C and has an emissivity of 0.9. The ambient air is at 23°C, and the road surface is at 28°C. The fluid properties of air are determined at the film temperature and can be found in the tables at the end of the tutorial. a. Determine the rate of heat transfer from the bottom surface of the engine block by convection and radiation as the car travels at a velocity of 60 km/h. [916W] b. If the temperatures were measured with a thermometer accurate to the nearest 1°C, what is the uncertainty in the resultant heat transfer rate? (You may ignore the uncertainties when calculating your fluid properties). [+10W] c. If the speedometer in the car is accurate to the nearest 2km/h, what is the uncertainty in the result? [+11W] [Uncertainties assumed as independent in all cases]See Answer
Q20:1. The SA Water desalination plant in Lonsdale was officially opened in 2013 to assist with fresh water supply during the 2000s drought. As we are no longer drought- stricken in South Australia, the plant currently operates at 10% of its 300 megalitre/day capacity. The sea water feeding the desalination plant along the coast of Lonsdale has a salinity value of 35 grams/litre. The brine (salty water) output from desalination plant is has a salinity of 75 grams/litre. The density of sea water can be assumed to be 1020kg/m3 and the density of the brine as 1050kg/m3. a. Determine the mass flow rates of the brine and pure water streams leaving the desalination plant in kg/hr. [6.125 * 105 kg/hr] b. If the salinity meter used to determine the salt content in the water is accurate to the nearest 1g/L and has a precision level of ±5%, determine the uncertainty in the flow rate of the brine. [Assuming independent ±4.4*104 kg/hr]See Answer

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